mole heading

Higher tier only

ream of paperChemists maybe calculating how much of substance A to add to substance B to get the reaction to go as expected, or calculating how much of a certain product they will be able to make if they start with X grams of substance A. One of the essential skills you must have as a good chemist is to be able to calculate how much of a particular reactant or product you will need or make. The problem is that atoms are by themselves far too small to weigh or count so counting atoms is a complete non-starter. What is needed is a quantity or number that will let them compare equal numbers of particles.

Chemists are not the only people faced with this problem, consider paper! You don't buy individual sheets of paper, you buy paper in reams. A ream contains 500 sheets of paper. A ream of A3 paper will be bigger than a ream of A4 paper because A3 paper is bigger than A4 paper- obviously! But a ream of A3 paper still contains 500 sheets of paper. The ream is a unit used by paper suppliers because it contains a standard number of sheets, 500 sheets. So if an order comes in for 10 000 sheets of paper would you rather count out 10 000 sheets of paper or quickly count out 20 reams?

a moleChemists like paper suppliers need a standard unit which they can use to measure out equal numbers of atoms/ions/molecules or particles. They don't use reams instead they use a unit called the mole. The word mole may seem an odd choice of a word, since most people think of moles as furry little gritters that dig up your lawn! The word mole is actually derived from a Latin word meaning mass or pile. 1 mole of a substance contains 6 x 1023 particles. So like the example above with paper, would you rather measure out 1 mole of a substance or count out 6 x 1023 atoms?

Measuring the mass of atoms

relative atomic massChemists use a relative atomic mass scale when we measure the mass of atoms (relative simply means compared to). In 1961 the isotope of carbon, 12C, was picked as the standard from which the masses of all other atoms would be compared. On the carbon-12 scale the 12C isotope is given an atomic mass of exactly 12. This means that 12 grams of 12C contains 1 mole of carbon atoms. That is 6 x1023 atoms.

On this scale the mass of magnesium is 24, since magnesium atoms are twice as "heavy" as carbon atoms. So we would say the relative atomic mass of magnesium is 24. This means that magnesium atoms have twice the mass of carbon atoms. The relative atomic mass of magnesium is therefore 24, we use the symbol Ar for relative atomic mass. So if we weigh out 24g of magnesium we will have the same number of atoms as we have in 12g of 12C, that is 1 mole of magnesium atoms. The only difference is the magnesium atoms are twice as massive as carbon atoms.

comparing massesSimilarly carbon atoms are 12 times as heavy as hydrogen atoms, so it follows that 12g of carbon and 1g of hydrogen contain the same number of atoms, that is 1 mole of atoms. The relative atomic mass in grams of all elements will contain 1 mole of atoms.

The mole and Avagadro

 1mole of carbon1 mole of carbon or 12 grams of carbon is quite a large pile of carbon and obviously atoms are very small, so there is going to be quite a large number of atoms in that pile of carbon. In fact it's an unbelievable huge number of carbon atoms, there are : 600 000 000 000 000 000 000 000 atoms of carbon in the charcoal block opposite! That is 6 x 1023 atoms. That's a lot! This number is often called Avagadro's number, after the Italian scientist Amedeo Avagadro. Imagine having to count them! Well that is why we don't, we weigh them. That is the beauty of the mole. By simply weighing out 12g of carbon we know exactly how many atoms we have. If you weigh out 1.2g of carbon, that is 1/10th of a mole or 0.1 moles then you can easily work out how many atoms of carbon you have:

1.2g of carbon=0.1 x 6x1023 = 6x102 atoms

1 mole of amgensium It follows then that 24g of magnesium, also contains 6 x 1023 atoms of magnesium
32g of sulfur also contains 6 x 1023 atoms of sulfur or
48g of titanium also contains 6 x 1023 atoms of titanium.
So by weighing out masses in grams or kilograms chemists have a way of counting atoms which is quick and also accurate.

Key points