Header image metal carbonates and neutralisation

Higher and foundation tiers

Antacids conatin the base calcium carbonate which will neutralise excess stomach acid.

Neutralisation using metal carbonates

Good bases include solid metal oxides, metal hydroxides (remember solutions of metal hydroxides are called alkalis) and metal carbonates. All these bases can be used to neutralise acids. Metal carbonates including calcium carbonate and magnesium carbonate are often used to neutralise acids. Calcium carbonate is the main ingredient in antacid tablets. Indigestion is caused by too much acid being produced in the stomach. To neutralise this excess acid a non-toxic base is need and calcium carbonate (or chalk) is ideal. Acids react with metal carbonates according to the equation below:

acid(aq) + metal carbonate(s) salt (aq) + water(l) + carbon dioxide(g)

Metal carbonate acid reactions

Copper carbonate reacting with hydrochloric acid

When metal carbonates reacts with acids they fizz due to the carbon dioxide gas which is released. The image opposite shows copper carbonate reacting with hydrochloric acid. The carbon dioxide gas which is released can be detected by simply bubbling it through a solution of limewater. The limewater will turn a milky or chalky colour in the presence of carbon dioxide gas. If an excess of calcium carbonate is added, that is more calcium carbonate than is actually needed to ensure the all the acid is neutralised, then when no more bubbles of carbon dioxide gas are seen then the acid has been neutralised.


Copper carbonate and hydrochloric acid

In the image opposite green copper carbonate is being used to neutralise hydrochloric acid. The salt produce here will be copper chloride, to obtain the solid copper chloride salt produced then the solution will need to be filtered and evaporated; this is outlined in the diagram below.

Neutralisation and metal carbonates- basic method

The method used to neutralise an acid using a metal carbonate is shown below. It is very similar to the method described earlier using copper oxide as a base. In the example below the metal carbonate used is calcium carbonate (chalk) and the acid used is hydrochloric acid.

Experimental details and set up for the neutralisation of an acid using a metal carbonate.

Everyday examples of neutralisation using metal carbonates

Rivers and lakes which have become badly affected by acid rain may have powdered limestone (calcium carbonate) added to them. These acidic rivers and lakes will see a loss of plant and animal species due to the adverse affects of acid rain caused by pollution, however these effects can be reversed by addition of a base such as calcium carbonate which will neutralise the acidic water in the lake and help restore some of the lost plant and animal species.

A plane spraying powdered limestone onto a lake to help deal with the problems caused by acid rain.

However this will only be a short term solution to the problems caused by the acid rain since to completely solve this problem the under lying issues which cause the acid rain in the first place will have to be dealt with. Spraying powdered limestone onto rivers and lakes using planes and helicopters is however an expensive and temporary solution to a major problem.

Everyday examples of neutralisation reactions using metal carbonates

A traditional home remedy to deal with bee stings; which are acidic is to add a thick paste made by mixing baking soda (sodium bicarbonate or baking soda) with a little added water to the bee sting. The baking soda contains sodium bicarbonate (Na2CO3) which is a basic substance which may be able to neutralise the acid present in the acidic bee sting and help relieve the pain.

Baking soda can be used to treat bee stings and toothpaste contains metal carbonates.

Some toothpastes also contain the basic substance calcium carbonate which acts as a mild abrasives to help remove stains, it also thicken the toothpaste and helps to neutralise any acids produced in the mouth to help reduce tooth decay.


Quick check questions

Released when an acid reacts with a metal carbonate
The test used to identify carbon dioxide gas.
The base found in indigestion tablets and toothpastes.
The base added to acidic lakes and rivers.
Calcium carbonate
Powdered limestone
Turns limewater milky
Carbon dioxide


Practice questions and self-check quiz

Check your understanding - Quick Quiz metal carbonates and acids

Check your understanding - Questions on metal carbonates and acids

Check your understanding - Additional questions on metal carbonates and acids

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