Higher and foundation tier

The non-metals

The non-metals are found on the left-hand side of the periodic table in groups 3,4,5,6,7 and group (0 or 8). Group 7 is called the halogens and group 8 (or 0) is called the Noble gases. The image shows an outline of where the non-metals are found in the periodic table.


Physical properties of non-metals

The physical properties of an element will depend largely on the type of structure it has and on the bonding present within the elements. The structure of the non-metal elements varies from the giant covalent network found for the group 4 elements e.g. carbon and silicon. however most of the non-metals have small molecular structures e.g. the halogens in group 7 all consist of small diatomic molecules, that is molecules made up of just 2 atoms. Whereas the Noble gases in group 0 do not react easily and consist of single atoms. Some of the physical properties of the non-metals elements are shown in the table below, where they are compared with those of metals.

physical property of a typical non-metal physical property of a metal
electrical insulator electrical conductor
thermal insulator thermal conductor
brittle (if solid) malleable
low density high density
low melting point high melting point
dull (if solid) shiny

The image below shows the type of structure for most of the non-metals you are likely to meet. You can see that the group 4 non-metals carbon and silicon have covalent giant structures but that groups 5, 6 and 7 non-metals have molecular structures. The Noble gases being almost inert consist of single atoms.

structures of non-metals

Group 5 non-metals

red and white phosphorus The group 5 elements nitrogen and phosphorus are the ones we need to consider. These two elements have small molecular structures. Nitrogen consists of two atoms joined together by a triple covalent bonds in a small diatomic molecule, N2. There are two common allotropes (types or forms) of phosphorus, white phosphorus which consists of a small molecule made of 4 phosphorus atoms joined in a tetrahedral shaped molecule, which is shown in the image above. The other allotrope is red phosphorus which is a polymer made by linking many P4 tetrahedrons together to form a long chain.

White phosphorus is highly reactive and bursts into flames when exposed to oxygen in the air, this is why it is stored under water. It is a very dangerous element to handle and is used by the military in bombs and grenades and is one of the main ingredients in napalm. These two elements have small molecular structures which consist entirely of covalent bonds, the small molecular structure means they have low melting and boiling points. White phosphorus has a melting point (m.p.) of 440C and its boiling point (b.p.) is 2800C. Nitrogen has a melting point of -2100C and its boiling point is -1950C.

Group 6 non-metals

group 6 non-metals The structure of two group 6 elements; sulfur and oxygen are shown opposite. Sulfur is a very common element and there are large underground deposits of elemental sulfur. Sulfur is one of the few elements that can be found relatively pure in the Earth's crust. It is a yellow solid with a molecular structure. There are many different allotropes (forms or types) of sulfur and many of them have sulfur atoms in rings. Some of these ring structures contain 6 sulfur atoms while other forms consist of ring structures containing up to 20 sulfur atoms. The most stable form at room temperature is the allotrope containing 8 sulfur atoms, formula S8, in the ring structure, shown in the image opposite.

Perhaps the most memorable fact about sulfur that you are likely to remember from using it in the lab is the really bad smell of many sulfur compounds. Burning sulfur produces sulfur dioxide, an irritating foul smell gas, which smells of rotten eggs. Hydrogen sulphide gas (H2S), forms when sulfur and hydrogen atoms join; this obnoxious smelling gas is used in stink bombs!!

Oxygen is a small diatomic molecule containing 2 atoms held in place by a double covalent bond between the two atoms. Like the elements in group 5 both sulfur and oxygen have a small molecular structur with low melting and boiling points. Sulfur melts at 1150C and boils at 4440C while oxygen, a much smaller molecule, has a m.p of -2190C and a b.p of -1830C. Like all substances with covalent bonds these non-metals are electrical insulators and will not conduct electricity. The reason for this is simply because all the electrons are held in covalent bonds and are not free to move as they are in metals

Group 7- The Halogens

Group 7 non-metals are called the halogens. The halogens are fluorine, chlorine, bromine and iodine. Astatine at the bottom of group 7 is a very rare and highly radioactive element. It has some uses in cancer treatments and other medical treatments.
The word halogen comes from the Greek words meaning salt-former, hals (salt) and gennan meaning to form. The halogens are all very reactive elements and are not found as elements in nature, instead they are found combined in compounds found in rocks and minerals.
They are all toxic and corrosive and great care is needed in handling these reactive elements, though iodine as the least reactive halogen and being a solid is the easiest and safest halogen to handle in the lab. The halogens all consist of small diatomic molecules which means they will have low melting and boiling points. The reactions and properties of the halogens are discussed in more detail on a separate page- The halogens. Fluroine and chlorine are coloured gases at room temperature. Fluorine is a green-yellowish gas similar in colour to chlorine but paler. Bromine is a reddish brown volatile liquid which produces very corrosive and toxic vapours. Iodine is a purple coloured solid with a reflective sheen. It sublimes with mild heating to form a beautiful violet coloured vapour.

Key Points

molecular structure of group5,6 and 7 elements

Practice questions

Check your understanding - Questions on non-metals